Synthesis of water dispersible alkyd resins were carried out in two ways. In order to save foreign currency out flow, it is needed to produce alkyd resin in myanmar. Fatty acids were liberated by the addition of water followed by. Alkyd resin synthesis by enzymatic alcoholysis springerlink. Alkyd resin constituents have been determined for decades, the method used being chemical cleavage followed by estimation by gravimetry, colorimetric or spectrophotometric means. There are continual developments to improve alkyd based formulations. Synthesis and characterization of yellow oleander thevetia peruviana seed oilbased alkyd resin. An alkyd typically consists of unsaturated fatty acids, polyols and phthalic anhydride as depicted in figure 1 1, 2. Alkyd resin was synthesized from the flamboyant delonix regia seed oil fbo and the physicochemical properties of both the oil and the consequent alkyd resin were studied. Alkyd based resins are frequently used in paints and coatings for a range of applications and still represent over 20% of the binder systems in use today. Synthesis and application of palm fatty acid distillate based. Optimization of polycondensation process of alkyd resin. Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as a catalyst.
Faster drying long oil alkyd resins are produced based on soybean oil used as sole film former for decorator paint. Present investigation was aimed to develop new methodology to synthesis alkyd resin from tpa and it was successfully achieved by altering the order of feeding raw materials and increasing the reaction temperature 260280 c. Pdf preparation and characterization of alkyd resins based on. Synthesis, characterization, and utilization in surface coating applications pirita ramanen academic dissertation for the degree of doctor of philosophy to be presented, with the permission of the faculty of science of. However, till today, there has been practically no information available for the synthesis of alkyds using ccso.
M o r e recent examples of alkyd resin preparation are shown in table vi. Synthesis of improved phenolic resins twenty seven addi ti on cured phenol ic resin compositions were prepared and tested for their abi 1 ity to give char residues comparable to stateof theart phenol ic resins. Alkyd resins technology handbook top results of your surfing alkyd resins technology handbook start download portable document format pdf and ebooks electronic books free online rating news 20162017 is books that can provide inspiration, insight, knowledge to the reader. There was probably crosslinking of the alkyd chains resulting in the formation of a large molecular weight polymer which could have resulted in increased viscosity of the reaction. The main reactions involved in alkyd resin synthesis are polycondensation by. Saponification of the alkyd resins was carried out by refluxing a 45 ml sample with saturated methanolic potassium hydroxide using an nz sparge for 10 min. The resins were characterised in terms of structure, molecular weight. But conventional alkyd making techniques cannot be apply for tpa due to its high stability and reaction temperature compare to the pa. Production of alkyd resin using water melon seed oil. Overview in the united states vinyl toluene has been used to modify alkyd resins for many years. The free fatty acid ffa value of the rubber seed oil rso and linseed oil.
Fourier transform infrared ftir spectroscopy was used to investigate. Mickael agach, stephanie delbaere, sinisa marinkovic, boris estrine, veronique nardellorataj. The resins produced are substantially colorfree and have a narrow range of. Synthesis of fast drying long oil alkyd resins using seed. Structures of obtained modified resins were confirmed by ftir method. This study was aimed at the synthesis and characterization of alkyd from. Optimization of polycondensation process of alkyd resin synthesis. The synthesis of an alkyd resin through an enzymatic alcoholysis provided by novozym 435 was analyzed in this study. Only trace free samples were considered as cured polymeric. Utilization of sunflower acid oil for synthesis of alkyd resin. Gift sample of commercial alkyd resin car was used as reference sample, obtained from perstorp india pvt. Alkyd resin manufacturing process, alkyd resin plants, alkyd resin processing projects, alkyd resin production business, alkyd resin production plant, alkyd resin production process, alkyd resin properties, alkyd resin reaction. Alkyd paint and paint driers metal catalysed reactions only peroxy radicals are of importance in chain propagation. An alkyd is a polyester resin commonly derived from fatty acids, polyhydric alcohol, and dibasic acids, which has many applications in the coatings industry due to its low cost, broad functionality, and production from renewable seed oils.
College affiliated to m j p rohilkhand university shahjahanpur, u. The potential of synthesizing an air drying alkyd resin through polycondensation of nondrying. The alkyd resin is mixed with a polymeric isocyanate and a metallic drier, which speeds the reaction. Present investigation was aimed to develop new methodology to synthesis alkyd resin from tpa and it was. A soya alkyd resin with 60% oil length was prepared by alcoholic process using 1200 g of soya oil, 280 g of pentaerythritol 2. Synthesis and characterization of hyperbranched silane. Synthesis and characterisation of alkyd resins with glutamic. Synthesis, characterization and performance evaluation of. Many industrial baking enamels, such as those for appliances, coil coatings, and automotive finishes, are based on alkyd amino resin blends. In order to promote public education and public safety, equal justice for all, a better informed citizenry, the rule of law, world trade and world peace, this legal document is hereby made available on a noncommercial basis, as it is the right of all humans to. Synthesis of resin having average molecular weight of about 370 and 1,2 epoxy. Synthesis of alkyd resin via alcoholysispolyesterification process. A typical oilmodified alkyd resin synthesis using linseed oil is given in preparation 22. Mar 09, 2017 most commonly used dibasic acid in alkyd synthesis is phthalic anhydride while glycerols, pentaerythritol, trimethylol propane, glycols etc.
Airdriable alkyd resins and process for their preparation download pdf. The invention provides alkyd resin for a woodware primer and a synthesis method of the alkyd resin. A water reducible alkyd acrylic resin resulted from a copolymer of 15 to 40% nbutylacrylate and maleic anhydride polymergrafted on modified palm kernel oil saravari, et al,2005. The traditional oils such as soya bean, coconut oil, sunflower oil, linseed oil are used in the synthesis of alkyd resin 811. Chemical modification of alkyd resin by a dopo derivative and its flame retardancy.
The oils that are mostly employed for alkyd resin synthesis are linseed oil, soya bean oil, dehydrated castor oil, fish oil and tall oil. Iodine value of the alkyd shows that the level of unsaturation depends on the oil length of the resins. In this research therefore, the effect of catalyst type and concentration on dehydrated castor oil based resin were examined. A lot of alkyd resins were imported to myanmar paint industries every year. The available manufacturer information on the resins was reported previously. A n analysis of the properties of the various oils is given in table iv. Its products originate from a polyhydric alcohol polyol, a polybasic acid, and a fatty monobasic acid, from seed oil. Uzoh cf, onukwuli od, emeka m 2015 kinetics of castor oil alkyd resin polycondensation reaction. Jul 29, 2019 the synthesis of an alkyd resin through an enzymatic alcoholysis provided by novozym 435 was analyzed in this study. In the synthesis a maximum content of 40% of cardanol in the resin was possible to obtain, as a higher cardanol content resulted in the formation of a resin with an extremely high viscosity. The synthesis method of the alkyd resin comprises the steps that the refined vegetable oil and 25 part by weight of polyatomic alcohol are put into a.
Without driers, the drying time of alkyd paint would be over 24 hours, which is clearly undesirable for most applications. The oil length is the weight percent of fatty acids in the finished resin. Synthesis and characterization of modified phenolic resins. The modified phenolic resins were prepared at various mole ratios of phenol to cardanol and the polymerization was carried out under basic conditions. Aug 31, 2019 the purpose of this paper is to introduce a new method for modification of alkyd resin by using 3triethoxysilylpropyl succinic acid anhydride tespsa as the core material for low volatile organic components vocs polyurethane coating applications. Modified alkyd resins as the versatile coating materials. The alcoholyses were performed in different enzyme concentrations 2. The type of alkyd resin used in artists alkyd paints is a long oil alkyd, which is an oilmodified polyester polymer that con tains between 5670 weight percent wt % fatty acids. If an alkyd resin contains sufficient monobasic acid and excess glycerol to. Synthesis and characterisation of alkyd resins with glutamic acidbased monomers joris hulsbosch, a laurens claes, a dries jonckheere, a dirk mestachb and dirk e. Alkyd was a term coined by kienle from alcohol and acid.
In the beginning, we have used pure ccso and a blend with prunus mahaleb as a substitute for fatty acids in order to synthesize a new alkyd resin. Alkyd is a term to describe special types of polyester resins that are modified with monobasic fatty acids. Us3639314a process for the preparation of highviscosity. Chemical modification of alkyd resin by a dopo derivative and. The modified alkyd resin can be dispersed in water up to 30 wt%. The early research resulting in alkyd resins was done by a number of researchers led by carothers 1 and kienle 2 who provided a clearer understanding of the chemical reactions governing alcoholacid polymeric resins from multifunctional monomers. Developed in the 1920s, alkyd based enamel paints were once one of the most important types of surface coating. Similarly, melon seed oil was found to be a substitute for linseed oil, and soyabean oil in the synthesis. Despite the growing popularity of acrylic, polyurethane and. Synthesis and characterization of novel silicone acrylate. Download for offline reading, highlight, bookmark or take notes while you read alkyd resins technology handbook. The alkyd resin is prepared from refined vegetable oil, polyatomic alcohol, polyatomic acid, a metal hydroxide catalyst and a xylene mixture.
In this work, glutamic acid as well as nacylated and nalkylated derivatives there of were evaluated as biobased substitutes for these aromatic diacid monomers in the synthesis of alkyd resins. Alkyd resins introduction classification drying nondrying synthesis fatty acid method. Kinetic studies in the synthesis of alkyd resin using. Cn105820320a alkyd resin for woodware primer and synthesis. Synthesis and application of palm fatty acid distillate based alkyd resin in liquid detergent. In spite of challenges from many new coating resins developed over the years, alkyd resins as a family have maintained a prominent position for two principal reasons, their high versatility and low cost. Synthesis and characterization of solvent free alkyd resin with hyperbranched melamine core submitted by nagehan keskin in partial fulfillment of the requirements for the. Chemical ijcpt synthesis and characterization of new. Alkyd paint and paint driers 11 catalysts, or driers. Saturated fatty acid yields nondyeing or plasticizing resin while drying properties are conferred by unsaturated acids. Cyanate, epoxy, a1 lyl, acrylate, methacrylate and. Alkyd resins include a very high proportion of common binders, which are used in the pants.
Pdf in this study, different samples of alkyd resins based on citrullus colocynthis. Alpha and, betahydroxyls of glycerol in preparation of. Pdf synthesis of waterborne alkyd resins researchgate. The analysis of alkyd resins was revolutionized in the 1960s by us government workers who determined the reaction products by gc. The main reactions involved in alkyd resin synthesis are polycondensation by esterification and ester interchange. Investigating the effect of catalyst type and concentration. Analysis of polyesters and alkyd resins pdf free download. It is a medium oil alkyd resin and it was produced by using soybean oil, glycerol, phthalic anhydride and benzoic acid. Besides these, other alkyds are also prepared, such as imidemodified alkyd. Preparation and characterization of alkyd resins based on. This supports the choice of methyl ester as a preferred alternative to the use of the raw rso in alkyd resin preparation.
Fatty acids for alkyd resins univar supplies a wide range of fatty acids from short oil to long oil that meet the exacting demands of alkyd resin curing requirements. Pdf synthesis and characterization of alkyd resin from. Alkyd resins manufacturing, formulation and processing. Ebook alkyd resins technology handbook as pdf download. Enhancing the quality of alkyd resins using methyl esters of. Alkyd resins technology handbook download ebook pdf. Alkyd amino resin blends are probably the most important group of alkyd resins. Alkyd resins, based on specific applications, are grouped be. Unlike most fast dry systems, the addition of vinyl toluene provides compatibility with both aliphatic and aromatic solvents giving the paint formulator a great deal of flexibility in formulating paints. Pdf synthesis and characterization of alkyd resin based.
Use of alkyd resins in paints and coatings the alkyd resins belong to the family of thermosetting polyesters, organic macromolecules obtained through the reaction between an acid or an anhydride, an alcohol and a fatty. Unlike other nobake mould technologies the process yields no toxic fumes, but the moulds need a longer air curing. In this study, a new alkyd based resin was formulated using long oil alkyd and melamine based hyperbranched polymer having 24 functional groups on its structure. Thermogravimetric analysis tga showed that dhdopo had relatively. Alkyd coatings are typically sold in three classes. Modified alkyd resins as the versatile coating materials derived from vegetable oils a hasnat natural product and polymer research laboratory, department of chemistry, g. Kinetics of castor oil alkyd resin polycondensation reaction. Pdf synthesis and characterization of alkyd resin from delonix. Alkyd resins are any of a large group of thermoset resins that are essentially polyesters made by heating polyhydric alcohol with polybasic acids or their anhydride and used chiefly in making protective coatings good weathering with properties. The resulting oils are used in alkyd resin preparation or as additive for coatings. With strong business partnerships with major oleochemical manufacturers around the globe, univar provides onestop access to a consistent and steady flow of products. Alkyd resins technology handbook download ebook pdf, epub. Palm oilbased alkyd resins were synthesized by alcoholoysis and esterification reactions.
Synthesis and characterisation of alkyd resins with. Chlorinated rubber is often used in combination with medium oil dryingtype alkyds. Chemical modification of alkyd resin by a dopo derivative. Alkyd resins lin major reference works wiley online. The term alkyd was coined from the combination of the words alcohol and acid. Download limit exceeded you have exceeded your daily download allowance.
Click download or read online button to get alkyd resins technology handbook book now. Alkyd resin manufacturing process, alkyd resin plants, alkyd resin processing projects, alkyd resin production business, alkyd resin production plant, alkyd resin production process, alkyd resin properties, alkyd resin reaction, alkyd resin synthesis, alkyd resins chemical technology, alkyd resins formulations, alkyd resins manufacture, alkyd resins manufacturing. Alkyd resin, a complex oilmodified polyester that serves as the filmforming agent in some paints and clear coatings. They are mainly composed of fatty acids, polyols and aromatic diacids. However, there is markedly lack of data and information in current literatures about synthesis of alkyd resin from delonix regia seed oil. Characterization of unsaturated polyester and alkyd resins. Synthesis of resin having average molecular weight of about 370 and 1,2 epoxy equivalency of 1. If an alkyd resin contains sufficient monobasic acid. Alkyd resins have acquired great importance because their economy, availability of raw materials, biodegradability, durability, flexibility, good adhesion and ease of application 7. Polynt is a historic leader in the chemical sector, a reference point in the production and sale of alkyd resins for paints.
Thus many researches have been successfully conducted on synthesis of watersoluble alkyd resin. Owing to their incorporation of volatile organic solvents and to. New alkyd resinswere synthesized by reacting sunflower oil or. International journal of chemistry and technology synthesis and. Alkyd resins introduction classification drying nondrying synthesis fatty acid method alcoholysis or monoglycerides method. This site is like a library, use search box in the widget to get ebook that you want. Materials the castor seeds shown in figure 1 were purchased from achi in orji river, enugu state. Most commonly used dibasic acid in alkyd synthesis is phthalic anhydride while glycerols, pentaerythritol, trimethylol propane, glycols etc.
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